CBSE Class 9 Science (Exploration) · Complete Notes · Read only this page → score 100%
- Acharya Kanada → parmanu
- Leucippus & Democritus → atomos
- Imaginary idea, no experiments
- First scientific atomic theory
- Atoms = indivisible building blocks
- Radioactivity discovered
- Atoms NOT indivisible!
- Cathode rays → electron
- First subatomic particle
- Plum pudding / watermelon
- + sphere with − electrons
- Are atoms the smallest indivisible particles?
- Why do electrons not fall into the nucleus even though they are attracted to protons in it?
- Why did scientists keep modifying atomic models?
- Everything you see, observe, or feel around is matter.
- Matter consists of tiny particles called atoms — both living beings (us) and non-living things (a house) are ultimately composed of atoms.
- Atoms are so tiny they cannot be seen with the naked eye.
- The big question of this chapter: Is the atom truly the smallest unit of matter, or can it be divided further?
8.1 Rediscovering the Roots of Atomic Theory
More than 2,000 years ago, thinkers in ancient India and ancient Greece asked the same question — What is everything made up of?
Acharya Kanada (India)
- If matter (dravya) is divided repeatedly, you reach the smallest particles that can no longer be divided.
- He called these particles parmanus.
- His ideas are recorded in the Sanskrit text Vaisesika Sutras.
- A parmanu is infinitely small and cannot be perceived by the senses.
- Parmanus combine to form dyads (groups of two) and triads (groups of three) — the whole material universe, including living bodies, is created from these combinations.
- Limitation: this description does not specify the proportions in which parmanus combine to form different substances.
Leucippus and Democritus (Greece)
- Proposed a similar idea of indivisible particles, calling them atomos.
- In Greek, atomos = indivisible.
The concept of the ‘atom’ originated as an imaginary idea, rather than from experimental observations.
John Dalton’s Atomic Theory (1808)
- In 1808, John Dalton proposed his atomic theory — based on scientific experiments of that time.
- All matter is composed of indivisible particles called atoms.
- Atoms are the fundamental building blocks of matter that cannot be broken down into smaller parts.
- It was the first scientific description of how matter is made — the starting point of atomic structure.
8.2 A Short Historical Journey Through Atomic Models
- Over a hundred years ago, scientists proposed simple models of the atom; as new experiments gave new evidence, the models were changed and improved.
- Early models were not fully correct, but they show how science moves forward — one step at a time, through curiosity, questioning, and experimentation.
- Until the late 19th century, atoms were thought to be indivisible. Then came the crack in the theory ⬇
Radioactivity: the phenomenon in which certain elements emit invisible energy and particles called radiation. It proved atoms are composed of smaller particles — they are NOT indivisible.
Discovery of the Electron — J. J. Thomson (1897)
- In 1897, J. J. Thomson studied the conduction of electric current through gases at very low pressure.
- Set-up: a glass tube with two electrodes + a high voltage applied.
- He observed rays moving from the cathode (− electrode) to the anode (+ electrode) — these were called cathode rays.
- By studying cathode rays in electric and magnetic fields, he concluded: they are streams of negatively charged particles with a much smaller mass than atoms.
- These particles, later called electrons, were emitted from atoms → atoms have smaller subatomic components.
- The nature of cathode rays was independent of the cathode material and the gas in the tube.
- Conclusion: electrons are a fundamental component of ALL atoms, present in every element.
- Charge of an electron = −1.602 × 10⁻¹⁹ C, taken as −1 as a matter of convention and convenience.
- Most significant discovery: the electron — the first subatomic particle to be identified, part of every atom.
- Received the Nobel Prize in Physics in 1906 for his studies of the electrical conductivity of gases.
- Head of the famous Cavendish Laboratory, Cambridge — guided many scientists, including Ernest Rutherford.
8.2.1 Thomson’s model of an atom
- Thomson’s puzzle: atoms are neutral — so where is the positive charge?
- His solution: the atom is a sphere of positive charge with electrons distributed throughout it.
- Compared to a pudding with plums embedded in it → the plum pudding model.
Red pulp = positively charged matter · Seeds = electrons distributed throughout the atom.
Though later replaced, this was the first genuine attempt to describe how the atom’s positive and negative charges stay balanced.
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- (i) Total negative charge > total positive charge → the model has a net negative charge → it does NOT represent a neutral atom.
- (ii) If the clay itself is negative, positive charge is missing entirely → total charge is negative → again NOT a neutral atom. Thomson’s model requires positive charge exactly balancing the electrons.
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- Matches: seeds (electrons) embedded inside soft pulp (positive charge) — same basic picture.
- Falls short: in an orange/lemon the seeds are clustered near the centre in segments, NOT distributed evenly throughout the pulp. Thomson’s model needs electrons spread uniformly through the whole sphere — the watermelon shows this better.
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- Cathode rays were identical regardless of the cathode material and the gas used in the tube.
- Since the same negative particles came from every substance tested, electrons must be a fundamental component of all atoms, in every element.
📝 Check Your Concepts — Part 1
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- Geiger & Marsden, under Rutherford
- α-particles → thin gold foil
- Most pass · some deflect · few bounce back
- Tiny dense + nucleus
- Atom mostly empty space
- Electrons orbit like planets
- Orbiting e⁻ should lose energy
- Spiral in → atom collapses
- Can’t explain stability
- By Rutherford
- + charge of nucleus
- Neutral atom: p = e
8.2.2 Testing Thomson’s model: The gold foil experiment
- In 1911, Geiger and Marsden, working under Ernest Rutherford, tested Thomson’s model through what became famous as the gold foil experiment.
- Set-up: a narrow beam of alpha particles aimed at an extremely thin sheet of gold foil.
Alpha (α) particles: tiny, positively charged particles emitted from certain radioactive elements. An alpha particle is actually a nucleus of a helium atom containing two protons and two neutrons.
- Expectation (as per Thomson’s model): positive charge is spread out evenly → α-particles should pass straight through or be deflected only slightly.
- Surprise observations: ① most particles passed through undeflected ② some were sharply deflected ③ a few even bounced back!
Scattering: the deflection of α-particles from their straight path. Hence, the gold foil experiment is also called an α-ray scattering experiment.
A. Rutherford’s model of an atom
From the gold foil experiment, Rutherford concluded that the positive charge of an atom is not spread throughout — it remains concentrated in an extremely small region called the nucleus. He proposed:
- Most of an atom is empty space — as most α-particles passed through the gold foil without any deflection.
- The nucleus is dense, contains all the positive charge and most of the mass of an atom.
- Electrons revolve around the nucleus, somewhat like planets orbiting the Sun → hence called the planetary model of the atom.
Diameter of atom ≈ 10⁻¹⁰ m · Diameter of nucleus ≈ 10⁻¹⁵ m
Memory trick: if the atom were a cricket ground (~100 m across), the nucleus would be a tiny black pepper grain (a few mm) at the centre!
Q: How many atoms make a sheet of paper 0.1 mm thick?
- Diameter of one atom ≈ 10⁻¹⁰ m; sheet thickness = 0.1 mm = 10⁻⁴ m.
- Number of atoms ≈ (10⁻⁴ m) ÷ (10⁻¹⁰ m) = 10⁶
- ≈ one million atoms stacked together! A simple sheet is a vast assembly of tiny building blocks, all neatly arranged.
Observe Fig. 8.4 of the gold foil experiment. Predict the observations you would expect if the gold foil were made thicker. Also, draw a simple diagram to show the observations you expect.
Hint: Compare thin foil vs thick foil. How does the thickness affect the chances of hitting a nucleus?
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- Thicker foil = more layers of atoms = higher chance of an α-particle passing close to (or hitting) a nucleus.
- So: more α-particles deflected, more bounce back, and fewer pass straight through compared to thin foil.
- Diagram idea: same beam, but now several bent arrows and 2–3 bounced-back arrows.
B. Limitations of Rutherford’s model
- From Chapter 4 (Describing Motion Around Us): a particle moving in a circular path is constantly changing direction → it is accelerating.
- An accelerating charged electron should lose energy.
- Losing energy → the electron would spiral inward and eventually fall into the positively charged nucleus.
- If that really happened → atoms would collapse and would not exist!
- But in reality, atoms are stable — matter around us stays intact.
- Conclusion: Rutherford’s model was not completely correct; a new explanation was needed for how electrons stay in motion without collapsing into the nucleus.
- Born in New Zealand; moved to Cambridge to work with J. J. Thomson.
- Known as the Father of Nuclear Physics.
- Discovered the atomic nucleus; explained how some elements naturally break down → 1908 Nobel Prize in Chemistry.
- In 1911, proposed the nuclear model of the atom. His portrait now appears on New Zealand’s $100 banknote.
C. Discovery of the proton
- Rutherford showed the nucleus carries positive charge, which comes from particles called protons (discovered and named by Rutherford).
- Protons are much heavier than electrons.
- Protons have a charge equal and opposite to that of electrons.
For an atom to be electrically neutral: number of protons = number of electrons.
Examples: helium → 2 protons, 2 electrons · sodium → 11 protons, 11 electrons. All atoms are electrically neutral.
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- Most particles would still pass through (atom is mostly empty space).
- But particles passing near a nucleus would be attracted TOWARD it (opposite charges attract) instead of being repelled away.
- So deflections would bend toward the nucleus, and no particle would be pushed back by repulsion the way α-particles were.
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- In the plum pudding model, positive charge is spread thinly and evenly across the whole atom.
- Such spread-out charge can never produce a force strong enough to reverse a fast, heavy α-particle.
- A bounce-back needs the positive charge and mass concentrated in one tiny, dense region → the nucleus. So the plum pudding picture cannot be correct.
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📝 Check Your Concepts — Part 2
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- Fixed shells = energy levels
- K, L, M, N (n = 1, 2, 3, 4)
- No energy loss in a fixed shell
- K closest → least energy
- Farther shell → higher energy
- Jump = absorb/release fixed energy
- He: 2 protons, but mass = 4 × H
- Something else in nucleus?
- Chadwick’s discovery
- Mass ≈ proton, charge 0
- In all nuclei except hydrogen
8.2.3 Bohr’s model of the atom
To explain why atoms are stable, Niels Bohr proposed a new model in 1913. According to Bohr:
- Electrons do not move randomly — they follow fixed circular paths called stationary states, orbits, or shells.
- In each shell, an electron has a definite amount of energy → shells are also called energy levels.
- Shells are represented by letters K, L, M, N, … or numbers n = 1, 2, 3, 4, …
- Electrons can revolve only in these allowed shells, not in between them.
- While moving in a fixed shell, an electron does not lose energy.
- The first energy level K (n = 1) is closest to the nucleus and has the least energy.
- Energy increases moving away from the nucleus: an electron in the L-shell (n = 2) has more energy than one in the K-shell (n = 1). The farther the shell, the higher its energy.
- An electron can move to another shell by absorbing or releasing a fixed amount of energy equal to the difference between the energies of the two levels.
- Each shell can hold only a certain number of electrons.
Bohr introduced stationary states as a postulate: in a stationary state, the energy of an electron remains constant, even though it is in motion around the nucleus. So electrons do not lose energy and do not spiral in. Bohr’s model explained many experimental observations — a major step in understanding atomic structure.
- The naming came from early X-ray experiments by physicist Charles Barkla, who called the first observed X-ray line K.
- He didn’t start from A — he left room for possible discovery of a series earlier than the K series (none were ever found).
- Bohr adopted the same notation for atomic shells.
- Professor of physics at Copenhagen University, Denmark.
- Curious about how atoms exist, because old models could not explain why electrons stay around the nucleus without collapsing.
- Received the Nobel Prize in 1922 for his work on the structure of the atom.
8.3 What Components Contribute to the Mass of an Atom?
- Rutherford’s model showed most of the mass of an atom is concentrated in its nucleus.
- Electrons are so light that their mass can be ignored.
- The puzzle (early 20th century): hydrogen has 1 proton, helium has 2 protons — yet helium’s mass is about FOUR times that of hydrogen, not double!
- Scientists wondered: besides protons, is there something else in the nucleus adding mass without affecting its charge?
8.3.1 Discovery of the Neutron
- In 1932, the problem was solved by James Chadwick (a student of Ernest Rutherford).
- He discovered a new subatomic particle with mass nearly equal to a proton but no electrical charge.
- This neutral particle was named the neutron, represented by the symbol ‘n’.
- Neutrons are found in the nucleus of all atoms except hydrogen.
- So, the mass of an atom comes mainly from its protons and neutrons packed tightly in the nucleus — this also explains why atoms are heavier than the mass of their total number of protons.
| S.No. | Subatomic particle | Symbol | Relative charge |
|---|---|---|---|
| 1. | Electron | e⁻ | −1 |
| 2. | Proton | p⁺ | +1 |
| 3. | Neutron | n⁰ | 0 |
- Lighter atoms often have equal protons and neutrons (carbon: 6 each; oxygen: 8 each).
- Heavier atoms have many more neutrons than protons: iron = 26 p, 30 n; uranium = 92 p, 146 n.
- Every proton repels every other proton (like charges). Neutrons, being neutral, reduce this repulsion by increasing the distance between protons — and by strengthening the nuclear force that binds all particles together.
- So heavier atoms need many more neutrons to hold the nucleus tightly bound.
- Worked under Rutherford at the famous Cavendish Laboratory, University of Cambridge.
- Discovered the neutron in 1932 — this breakthrough explained atomic mass.
- Earned the Nobel Prize in Physics in 1935. The neutron transformed research, enabling scientists to probe nuclear secrets and sparking a chain of discoveries in harnessing atomic energy.
- The Bhabha Atomic Research Centre (BARC), Mumbai, leads advanced neutron-scattering experiments using reactors such as Dhruva.
- This has revealed key insights into materials like superconductors, battery electrodes, and drug molecules — helping develop better medicines, energy storage, and industrial alloys right here in India.
- Activity: research and explore more about Dhruva!
📝 Check Your Concepts — Part 3
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- Dalton 1803: pictorial
- Berzelius 1813: Latin names
- Today: IUPAC approves
- Z = number of protons
- Decides element’s identity
- Neutral atom: p = e
- A = protons + neutrons
- p + n = nucleons
- Electron mass ignored
- A on top, Z below
- Example: ¹²₆C
8.4 Symbols of Elements
- John Dalton realised the need for a standard way to represent elements and compounds, to make the study of chemistry easier.
- In 1803, he introduced the first pictorial symbols to represent the known elements.
- In 1813, Berzelius suggested that symbols should be derived from the Latin names of elements → thus came alphabetic chemical symbols.
- Nowadays, the International Union of Pure and Applied Chemistry (IUPAC), an international scientific organisation, approves the names and symbols of elements.
Norms of writing symbols (IUPAC)
- Many symbols are the first letter or first two letters of the element’s name.
- The first letter is always CAPITAL; the second letter (if any) is always small. Examples: hydrogen, H; aluminium, Al (not AL); cobalt, Co (not CO).
- Some symbols use the first letter + a letter other than the second: chlorine, Cl; zinc, Zn.
- Some symbols come from Latin, Greek, or German names: iron = Fe (Latin ferrum), mercury = Hg (Greek hydrargyros), tungsten = W (German wolfram).
| Element | Symbol | Element | Symbol | Element | Symbol |
|---|---|---|---|---|---|
| Aluminium | Al | Copper (Cuprum) | Cu | Nitrogen | N |
| Argon | Ar | Fluorine | F | Oxygen | O |
| Barium | Ba | Gold (Aurum) | Au | Potassium (Kalium) | K |
| Boron | B | Hydrogen | H | Silicon | Si |
| Bromine | Br | Iodine | I | Silver (Argentum) | Ag |
| Calcium | Ca | Iron (Ferrum) | Fe | Sodium (Natrium) | Na |
| Carbon | C | Lead (Plumbum) | Pb | Sulfur | S |
| Chlorine | Cl | Magnesium | Mg | Uranium | U |
| Cobalt | Co | Neon | Ne | Zinc | Zn |
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- Confusion — the same symbol could mean different elements to different scientists.
- Research could not be shared, compared, or verified across countries and languages.
- Chemical formulas and equations would become unreadable — international collaboration would break down.
8.5 Atomic Number
The number of protons in the nucleus of an atom of an element is known as its atomic number, designated by the symbol Z. This number determines the identity of an element and its chemical behaviour.
- Atoms of one element are all alike, but different from atoms of other elements — they differ in the number of electrons and protons.
- Since the atom as a whole is neutral: number of protons = number of electrons orbiting the nucleus.
- Hydrogen: 1 proton, 1 electron → Z = 1. Helium: Z = 2 → 2 protons, 2 electrons.
- The atomic number uniquely identifies an element.
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8.6 Mass Number
- Helium has 2 protons, but its mass is about four times that of a proton — the extra mass comes from neutrons.
The total number of protons and neutrons in the nucleus of an atom is called its mass number, denoted by A. The protons and neutrons present in the nucleus are called nucleons.
Since a neutron’s mass ≈ a proton’s mass, helium’s mass = 2 protons + 2 neutrons = 4 units.
| Element | Protons (p⁺) | Neutrons (n⁰) | Mass number (A) |
|---|---|---|---|
| Hydrogen | 1 | 0 | 1 |
| Helium | 2 | 2 | 4 |
| Lithium | 3 | 4 | 7 |
- The electron, in comparison, has almost negligible mass — it can be ignored in calculations.
In the standard notation: Mass Number (A) is written on top, Atomic Number (Z) at the bottom, before the Symbol of the element.
Example: carbon → symbol C, atomic number 6, mass number 12 → written as 126C.
📍 So far: protons + neutrons live in the nucleus; electrons move around the nucleus.
🧮 Numerical Practice (NCERT Pause and Ponder) — try first, then check!
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📝 Check Your Concepts — Part 4
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- Max per shell = 2n²
- Outermost max = 8
- Fill stepwise: K → L → M
- Distribution of e⁻ in shells
- e.g. Na = 2, 8, 1
- Outermost shell = valence shell
- 8 e⁻ = octet → stable
- < 4 valence e⁻ → lose
- > 4 valence e⁻ → gain
- Carbon (4) → shares
8.7 How Are Electrons Distributed in Different Energy Levels?
Bohr and Bury suggested the following rules:
- The maximum number of electrons in a shell is given by the formula 2n², where ‘n’ is the number of the shell.
- The maximum number of electrons in the outermost shell is 8 (the first shell can hold a maximum of two).
- Electrons fill shells in a stepwise manner, starting closest to the nucleus and moving outward: K, L, M, N, … The L-shell fills only after the K-shell is complete, and so on.
- K-shell (n = 1): 2 × 1² = 2 electrons
- L-shell (n = 2): 2 × 2² = 8 electrons
- M-shell (n = 3): 2 × 3² = 18 electrons
- Hydrogen (Z = 1): its only electron has to be in the K-shell.
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8.7.1 Building up atoms
- We build 2-D atomic structures by adding one electron to the appropriate energy level each time the atomic number increases by 1.
The distribution of electrons among various shells is known as the electronic configuration of the atom.
| Element | Symbol | Atomic number | Protons | Neutrons | Electrons | K | L | M | N |
|---|---|---|---|---|---|---|---|---|---|
| Hydrogen | H | 1 | 1 | – | 1 | 1 | – | – | – |
| Helium | He | 2 | 2 | 2 | 2 | 2 | – | – | – |
| Lithium | Li | 3 | 3 | 4 | 3 | 2 | 1 | – | – |
| Beryllium | Be | 4 | 4 | 5 | 4 | 2 | 2 | – | – |
| Boron | B | 5 | 5 | 6 | 5 | 2 | 3 | – | – |
| Carbon | C | 6 | 6 | 6 | 6 | 2 | 4 | – | – |
| Nitrogen | N | 7 | 7 | 7 | 7 | 2 | 5 | – | – |
| Oxygen | O | 8 | 8 | 8 | 8 | 2 | 6 | – | – |
| Fluorine | F | 9 | 9 | 10 | 9 | 2 | 7 | – | – |
| Neon | Ne | 10 | 10 | 10 | 10 | 2 | 8 | – | – |
| Sodium | Na | 11 | 11 | 12 | 11 | 2 | 8 | 1 | – |
| Magnesium | Mg | 12 | 12 | 12 | 12 | 2 | 8 | 2 | – |
| Aluminium | Al | 13 | 13 | 14 | 13 | 2 | 8 | 3 | – |
| Silicon | Si | 14 | 14 | 14 | 14 | 2 | 8 | 4 | – |
| Phosphorus | P | 15 | 15 | 16 | 15 | 2 | 8 | 5 | – |
| Sulfur | S | 16 | 16 | 16 | 16 | 2 | 8 | 6 | – |
| Chlorine | Cl | 17 | 17 | 18 | 17 | 2 | 8 | 7 | – |
| Argon | Ar | 18 | 18 | 22 | 18 | 2 | 8 | 8 | – |
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- (i) Carbon: Z = 6 → config 2, 4 → outermost shell has 4 electrons.
- (ii) Fluorine: Z = 9 → config 2, 7 → outermost shell has 7 electrons.
- (iii) Silicon: Z = 14 → config 2, 8, 4 → outermost shell has 4 electrons.
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8.8 Combining Capacity of an Atom: Valency
The number of atoms of hydrogen or chlorine with which one atom of an element can combine to form a compound is called its combining capacity. It is expressed in terms of hydrogen and chlorine because both possess a combining capacity of one.
- Example: in H₂O (water), oxygen combines with two hydrogen atoms → combining capacity of oxygen = 2.
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Valence shell, valence electrons and the octet
- The outermost shell containing electrons is the valence shell; electrons in it are valence electrons.
- If the outermost shell has 8 electrons, it is called an octet.
- Elements with a complete octet (8 electrons) — or 2 electrons in the case of helium — are largely unreactive and more stable.
- Atoms with incomplete valence shells are usually more reactive — they lose, gain, or share electrons to complete their octet.
The number of electrons gained, lost, or shared to complete the octet is called the valency of the element.
- Fewer than 4 valence electrons → tends to LOSE electrons to complete its octet. Example: sodium (2, 8, 1) → loses 1 electron → valency 1.
- More than 4 valence electrons → tends to GAIN electrons. Example: oxygen (2, 6) → gains 2 electrons → valency 2.
- Exactly 4 valence electrons → cannot easily gain or lose → SHARES. Example: carbon (2, 4) → shares 4 electrons → valency 4.
- Some compounds appear to violate the usual valency rule — you will learn about them in higher grades.
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Show Answer — Valency Column
(Rule: valence e⁻ < 4 → valency = valence e⁻; valence e⁻ > 4 → valency = 8 − valence e⁻; octet/duplet complete → 0.)
📝 Check Your Concepts — Part 5
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- Same Z, different A
- H: protium, deuterium, tritium
- C: C-12, C-13, C-14
- Chemical properties SAME
- Physical properties differ
- Weighted by abundance
- Cl = 35.5 u
- Same A, different Z
- Ca-40, K-40, Ar-40
8.9 A Deeper Look into Atomic Structure
8.9.1 Isotopes
- Dalton proposed all atoms of an element are identical with the same mass — but scientists later discovered atoms of the same element with the same protons (Z) yet different neutrons → different mass numbers (A = p⁺ + n⁰).
Isotopes: ‘twin atoms’ with the same atomic number but different mass numbers.
Example 1: Isotopes of hydrogen
- Naturally occurring hydrogen is a mixture of three isotopes: 11H (protium, ~99.98%), 21H (deuterium, ~0.015%), and 31H (tritium, in traces).
- All contain one proton each; deuterium has one neutron, tritium has two neutrons.
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Isotopes have the same number of electrons and the same electronic configuration. Chemical properties depend mainly on valence electrons → all isotopes show the same chemical properties. They differ only in physical properties, e.g. boiling and melting points.
Example 2: Isotopes of carbon
- Carbon has three isotopes: 126C, 136C, and 146C. Each has six protons and six electrons.
- 126C is the most abundant isotope in nature. The three differ only in the number of neutrons (6, 7, 8).
- 23592U (uranium isotope) → used as fuel in a nuclear reactor to generate electricity in a nuclear power plant.
- 6027Co (radioactive cobalt isotope) → used in radiation treatment for cancer.
- 13153I (iodine isotope) → used to treat goitre and thyroid cancer.
- 146C (carbon isotope) → used in archaeology and geology to determine the age of ancient fossils and artefacts.
A. Average atomic mass
- Chlorine occurs in nature in two isotopic forms: mass 35 u and mass 37 u, in the ratio 3 : 1.
- The question: should we call the mass of a chlorine atom 35 u or 37 u?
Simple arithmetic mean of isotope masses, without accounting for relative abundances:
Average atomic mass = (35 + 37) ÷ 2 = 36 u
❌ But this does NOT accurately reflect nature — isotopes do not occur in equal ratios!
³⁵Cl ≈ 75% of natural chlorine; ³⁷Cl ≈ 25%. Multiply each isotope’s mass by its percent relative abundance, then add:
= (35 × 75/100) + (37 × 25/100)
= 105/4 + 37/4
= 142/4
= 35.5 u ✅
No single chlorine atom has a fractional mass of 35.5 u! It means: in 1 million chlorine atoms, there are 7.5 lakh 3517Cl and 2.5 lakh 3717Cl atoms, with a weighted average atomic mass of 35.5 u. The simple average ignores abundance; the weighted average atomic mass accurately reflects the mass of the element as it occurs in nature.
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- Atomic numbers: both Z = 11 (same).
- Mass numbers: 11+12 = 23 and 11+13 = 24 (different).
- Same Z → they are the SAME element (sodium) — they are isotopes of each other.
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= 39.263 + 40.743
= 80.006 u ≈ 80.01 u
8.9.2 Isobars
- Consider three elements: calcium (Z = 20), potassium (Z = 19), and argon (Z = 18).
- Different numbers of protons — yet each has a mass number of 40 → same total number of nucleons, though they are different elements.
Isobars: atoms of different elements with the same mass number but different atomic numbers.
The story does not end here…
- Later, scientists discovered that even Bohr’s model was not entirely correct.
- Electrons do not follow well-defined paths like fixed Bohr orbits — today we understand they exist as ‘electron clouds’ around the nucleus.
- We can predict regions where electrons are most likely to be, not exactly where they are. You will learn these details in higher grades — the journey of exploring the atom is far from over!
At a Glance (NCERT Summary)
- Atoms are the building blocks of matter.
- J. J. Thomson proposed that in an atom, electrons are embedded in a positively charged sphere.
- Rutherford’s model described the atom as mostly empty space, with a dense, positively charged nucleus at its centre and electrons orbiting it.
- Niels Bohr’s model proposed that electrons move in fixed energy levels (shells) around the nucleus.
- The shells of an atom are named as K, L, M, N, and so on.
- James Chadwick discovered the presence of neutrons in the atom.
- The three subatomic particles of an atom are electrons, protons, and neutrons.
- If the outermost shell of an atom has an octet of electrons (or two electrons in case of helium), the atom is stable and largely unreactive.
- Valency is the combining capacity of an atom. It is equal to the number of electrons which can be gained, lost or shared by an atom to achieve a stable configuration.
- The atomic number of an element is equal to the number of protons in its nucleus.
- The mass number of an atom is equal to the total number of nucleons (protons and neutrons) in its nucleus.
- Isotopes are atoms of same element that have the same atomic number but different mass numbers.
- The average atomic mass of an element is calculated based on the relative abundance of its isotopes in nature.
- Isobars are atoms of different elements with the same mass number but different atomic numbers.
Revise, Reflect, Refine (NCERT Exercises)
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- (i) ❌ Incorrect — neutrons were discovered by Chadwick in 1932, much later; the gold foil experiment revealed nothing about neutrons.
- (ii) ✅ Correct — sharp deflections and bounce-backs could not happen if positive charge were spread out evenly → plum pudding disproved, nucleus proposed.
- (iii) ✅ Correct — only a tiny, dense centre holding most of the mass and all positive charge can bounce back a fast α-particle.
- (iv) ❌ Incorrect — the deflections were caused by the nucleus repelling α-particles; the experiment gave no direct information about how electrons move.
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- (i) ❌ Incorrect — in a fixed shell (stationary state), an electron does not lose energy, so it never spirals into the nucleus.
- (ii) ❌ Incorrect — electrons exist only in allowed shells, each with a definite energy.
- (iii) ✅ Correct — this is Bohr’s central postulate: fixed-energy orbits with no energy loss.
- (iv) ❌ Incorrect — electrons revolve only in allowed shells, not in between them; they jump between levels by absorbing/releasing fixed energy.
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- (i) Y and Z: same atomic number (17), different mass numbers (35, 37) → they are ISOTOPES (both are chlorine).
- (ii) Z and X: same mass number (37), different atomic numbers (17, 18) → they are ISOBARS.
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- The positive charge is not spread throughout the atom — it is concentrated in an extremely small region at the centre, called the nucleus.
- The nucleus is dense and contains all the positive charge and most of the mass of the atom — only such a centre could repel fast α-particles straight back.
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- (iv) Dalton (1808): atoms are indivisible particles — the first scientific theory.
- (ii) Thomson (after discovering the electron, 1897): atom = positive sphere with electrons embedded (plum pudding).
- (iii) Rutherford (1911): gold foil experiment → atoms have a dense central nucleus, mostly empty space.
- (i) Bohr (1913): electrons move in fixed orbits (energy levels), explaining atomic stability.
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- (i) Protons = Z = 12
- (ii) Neutrons = A − Z = 24 − 12 = 12
- (iii) Electrons = protons = 12 (neutral atom)
- Arrangement: 2, 8, 2 → K-shell: 2 electrons, L-shell: 8 electrons, M-shell: 2 electrons (draw nucleus + three circles with 2, 8, 2 dots).
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| (a) 2, 1 | (b) 2, 5 | (c) 2, 8, 3 | (d) 2, 7 | |
|---|---|---|---|---|
| Name | Lithium | Nitrogen | Aluminium | Fluorine |
| Symbol | Li | N | Al | F |
| Total electrons | 3 | 7 | 13 | 9 |
| Valence electrons | 1 | 5 | 3 | 7 |
| Valency | 1 | 3 | 3 | 1 |
| Protons | 3 | 7 | 13 | 9 |
| Atomic number | 3 | 7 | 13 | 9 |
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- Rutherford: an electron in a circular path is accelerating → it should continuously lose energy, spiral inward, and fall into the nucleus → atom collapses. He had no answer for why this doesn’t happen.
- Bohr: introduced stationary states as a postulate — electrons revolve only in fixed allowed orbits where their energy remains constant. No energy loss in a fixed shell → no spiralling → atom is stable.
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| Atomic number | Mass number | Neutrons | Protons | Electrons | Element |
|---|---|---|---|---|---|
| 5 | 11 | 6 | 5 | 5 | Boron |
| 7 | 14 | 7 | 7 | 7 | Nitrogen |
| 12 | 24 | 12 | 12 | 12 | Magnesium |
| 15 | 31 | 16 | 15 | 15 | Phosphorus |
| 1 | 1 | 0 | 1 | 1 | Hydrogen |
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- (i) Protons = A − n = 35 − 18 = 17; electrons = 17.
- (ii) Atomic number Z = 17.
- (iii) X is Chlorine (Cl).
- (iv) Electronic configuration: 2, 8, 7.
- (v) Valence electrons = 7.
- (vi) New mass number = 35 + 2 = 37.
- (vii) Same Z (17), different A (35 vs 37) → they are ISOTOPES.
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- (i) Atomic number: unchanged (12) — Z depends only on protons.
- (ii) Atomic mass: increases — the heavy particles’ mass (500 × electron mass each) is no longer negligible, so the total mass of the atom goes up.
- (iii) Mass number: unchanged (24) — A counts only nucleons (protons + neutrons), not the orbiting particles.
- (iv) Overall charge: unchanged (neutral) — the particles carry the same charge as electrons, so 12 positive protons still balance 12 negative particles.
The Journey Beyond (NCERT Activities)
- Create an ‘Atomic Prediction Board’ game based on atomic number, mass number, number of electrons, protons, neutrons and valency. Students may predict elements using atomic clues.
- Prepare a report on how the properties of atoms impact us in everyday life across fields, such as healthcare, energy, agriculture and technology.
- Create a role-play, stage play or story about the ‘Journey Inside the Atom’, and the scientists who discovered and contributed to the identification of atomic structure.
- Use selected software or digital tools and try to create animations or simulations of various atomic models, and share them in the class.
- Watch a film or documentary about the structure of the atom and write a report answering: which film and its main idea; what it taught about atomic structure and model(s); which scientists were mentioned and their contributions; the most interesting part and a question you still have.
- Draw a bar graph showing the number of electrons in each energy level for any three elements.
- To learn more about atoms, explore: phet.colorado.edu/en/simulations/rutherford-scattering and phet.colorado.edu/en/simulations/isotopes-and-atomic-mass
Is it possible to completely understand everything that happens inside an atom?
